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Journal articlePearson VK, Sephton MA, Gilmour I, 2006,
Molecular and isotopic indicators of alteration in CR chondrites
, METEORITICS & PLANETARY SCIENCE, Vol: 41, Pages: 1291-1303, ISSN: 1086-9379- Author Web Link
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- Citations: 17
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Journal articlePerry RS, Sephton MA, 2006,
Desert varnish: an environmental recorder for Mars
, ASTRONOMY & GEOPHYSICS, Vol: 47, Pages: 34-35, ISSN: 1366-8781- Author Web Link
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- Citations: 13
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Journal articleSephton MA, James RH, Zolensky ME, 2006,
The origin of dark inclusions in Allende: New evidence from lithium isotopes
, METEORITICS & PLANETARY SCIENCE, Vol: 41, Pages: 1039-1043, ISSN: 1086-9379- Author Web Link
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- Citations: 15
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Journal articlePearson VK, Sephton MA, Franchi IA, et al., 2006,
Carbon and nitrogen in carbonaceous chondrites:Elemental abundances and stable isotopic compositions
, METEORIT PLANET SCI, Vol: 41, Pages: 1899-1918, ISSN: 1086-9379 -
Journal articleSephton MA, Howard LE, Bland PA, et al., 2006,
Delving into Allende's dark secrets
, ASTRON GEOPHYS, Vol: 47, Pages: 37-38, ISSN: 1366-8781 -
Journal articleMeredith W, Sun C-G, Snape CE, et al., 2006,
The use of model compounds to investigate the release of covalently bound biomarkers via hydropyrolysis
, ORG GEOCHEM, Vol: 37, Pages: 1705-1714 -
Journal articleMartins Z, Watson JS, Sephton MA, et al., 2006,
Free dicarboxylic and aromatic acids in the carbonaceous chondrites Murchison and Orgueil
, Meteoritics & Planetary Science, Vol: 41, Pages: 1073-1080, ISSN: 1086-9379 -
Conference paperSephton MA, Self S, Verchovsky AB, et al., 2006,
Carbon isotopic gradients in the Martian crust: implications for past or present life on Mars
, Conference on Instruments, Methods, and Missions for Astrobiology IX, Publisher: SPIE-INT SOC OPTICAL ENGINEERING, ISSN: 0277-786X -
Book chapterWestall F, de Vries ST, Nijman W, et al., 2006,
The 3.466 Ga Kitty’s Gap Chert, an Early Archean microbial ecosystem
, Processes on the early Earth, Editors: Reimold, Gibson, Publisher: Geological Society of Amer, ISBN: 9780813724058 -
Conference paperMartins Z, Botta O, Fogel ML, et al., 2006,
Isotopic analysis of nucleobases in the Murchison meteorite
, METEORIT PLANET SCI -
Journal articleEhrenfreund P, Sephton MA, 2006,
Carbon molecules in space: from astrochemistry to astrobiology
, FARADAY DISCUSSIONS, Vol: 133, Pages: 277-288, ISSN: 1359-6640- Author Web Link
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- Citations: 103
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Journal articleCourt RW, Sephton MA, Parnell J, et al., 2006,
The alteration of organic matter in response to ionising irradiation: Chemical trends and implications for extraterrestrial sample analysis
, Geochimica et Cosmochimica Acta, Vol: 70, Pages: 1020-1039Ionising radiation is an energy source capable of generating and altering complex organic matter. A full understanding of the radiolytic formation and devolution of organic matter is essential to appreciate the budget of organic chemicals that exist in cometary and interstellar ices, carbonaceous meteorites, and to understand the results of analyses of irradiated extraterrestrial organic matter, such as that in cometary nuclei. The effects of ionising radiation on a set of 10 naturally occurring, terrestrial organic assemblages have been revealed by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS), carbon isotopic analysis, and stepped combustion-isotope ratio mass spectrometry (SC-IRMS). Progressive radiolytic alteration of biogenic complex-hydrocarbon mixtures induces a decrease in the average size and extent of alkylation of polyaromatic hydrocarbons (PAH) and an increase in the abundance of oxygen-containing compounds, as indicated by Py-GC-MS, and an enrichment in C-13. These changes are attributed to reactions with free radicals, produced by ionising radiation. In contrast, the progressive radiolytic alteration of bitumens proposed to have derived from the radiolytic polymerisation of methane into an organic solid produces, upon pyrolysis, PAH of increasing average size and degree of alkylation. This, the opposite of the trend observed in the irradiated complex-hydrocarbons mixtures, cannot be explained in terms of the radiolytic alteration of a pre-existing array of complex organic molecules. Instead, it suggests the gradual construction of PAH from smaller molecules, supporting the hypothesis of a methane origin. Radiolytic alteration is also associated with a previously unrecognised increase in the mean combustion temperature of organic matter. This leads to predictions regarding the combustion characteristics of the irradiated organic matter present on cometary nuclei. A full understanding of the relationship between the combustion characteristics
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Book chapterBland PA, Zolensky ME, Benedix GK, et al., 2006,
Weathering of chondritic meteorites
, Meteorites and the Early Solar System II, Editors: Lauretta, McSween, Lauretta, McSween, Arizona, Publisher: University of Arizona Press, Pages: 853-867, ISBN: 9780816525621 -
Conference paperSephton MA, Perry RS, Hoover RB, 2006,
Thiophenes as indicators of aqueous alteration in carbonaceous meteorites
, Conference on Instruments, Methods, and Missions for Astrobiology IX, Publisher: SPIE-INT SOC OPTICAL ENGINEERING, ISSN: 0277-786X- Author Web Link
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- Citations: 4
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Journal articlePerry RS, Lynne BY, Sephton MA, et al., 2006,
Baking black opal in the desert sun: the importance of silica in desert varnish, 2006, Geology, 34, 537-540
, Geology, Vol: 34, Pages: 537-540, ISSN: 0091-7613 -
Journal articleSephton MA, 2005,
Organic matter in carbonaceous meteorites: past, present and future research
, PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, Vol: 363, Pages: 2729-2742, ISSN: 1364-503X- Cite
- Citations: 43
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Journal articleBada JL, Sephton MA, Ehrenfreund P, et al., 2005,
New strategies to detect life on Mars
, ASTRONOMY & GEOPHYSICS, Vol: 46, Pages: 26-27, ISSN: 1366-8781- Cite
- Citations: 25
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Journal articleSephton MA, Looy CV, Brinkhuis H, et al., 2005,
Catastrophic soil erosion during the end-Permian biotic crisis
, GEOLOGY, Vol: 33, Pages: 941-944, ISSN: 0091-7613- Cite
- Citations: 237
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Journal articleSephton MA, Love GD, Meredith W, et al., 2005,
Hydropyrolysis: A new technique for the analysis of macromolecular material in meteorites
, PLANETARY AND SPACE SCIENCE, Vol: 53, Pages: 1280-1286, ISSN: 0032-0633- Author Web Link
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- Citations: 27
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Journal articleVerchovsky AB, Sephton MA, 2005,
A noble record
, ASTRONOMY & GEOPHYSICS, Vol: 46, Pages: 12-14, ISSN: 1366-8781- Cite
- Citations: 1
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