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• Journal article
  McCall KL, Jennings JR, Wang H, Morandeira A, Peter LM, Durrant JR, Yellowlees LJ, Robertson Net al., 2011,

  Dinuclear Ru-Cu Complexes: Electronic Characterisation and Application to Dye-Sensitised Solar Cells

  , EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Pages: 589-596, ISSN: 1434-1948
  • Author Web Link
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  • Citations: 12
• Journal article
  Faist MA, Keivanidis PE, Foster S, Woebkenberg PH, Anthopoulos TD, Bradley DDC, Durrant JR, Nelson Jet al., 2011,

  Effect of Multiple Adduct Fullerenes on Charge Generation and Transport in Photovoltaic Blends with Poly(3-hexylthiophene-2,5-diyl)

  , JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, Vol: 49, Pages: 45-51, ISSN: 0887-6266
  • Author Web Link
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  • Citations: 58
• Journal article
  Eng MP, Shoaee S, Molina-Ontoria A, Gouloumis A, Martin N, Durrant JRet al., 2011,

  Impact of concentration self-quenching on the charge generation yield of fullerene based donor-bridge-acceptor compounds in the solid state

  , PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol: 13, Pages: 3721-3729, ISSN: 1463-9076
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  • Citations: 14
• Journal article
  Donaghey JE, Ashraf RS, Kim Y, Huang ZG, Nielsen CB, Zhang W, Schroeder B, Grenier CRG, Brown CT, D'Angelo P, Smith J, Watkins S, Song K, Anthopoulos TD, Durrant JR, Williams CK, McCulloch Iet al., 2011,

  Pyrroloindacenodithiophene containing polymers for organic field effect transistors and organic photovoltaics

  , Journal of Materials Chemistry, Vol: 21, Pages: 18744-18752, ISSN: 0959-9428

  The synthesis of the novel electron-rich pyrroloindacenodithiophene (NIDT) unit is reported. Stille copolymerization of the distannylated NIDT unit, with the electron-deficient dibrominated benzothiadiazole (BT), difluorobenzothiadiazole (ffBT), thienopyrrolodione (TPD) and 1,1[prime or minute]-bithienopyrrolodione (biTPD) units afforded a series of low band gap semiconducting polymers. Initial testing shows promise for the use of these materials as p-type semiconductors in organic field effect transistors (OFETs) with mobilities as high as 0.07 cm2V-1s-1 being measured. These materials have also been tested as the donor polymer in polymer/fullerene bulk heterojunction organic photovoltaics (OPVs) giving maximum efficiencies of 2.5%.

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• Journal article
  Schroeder BC, Nielsen CB, Kim YJ, Smith J, Huang Z, Durrant J, Watkins SE, Song K, Anthopoulos TD, McCulloch Iet al., 2011,

  Benzotrithiophene Co-polymers with High Charge Carrier Mobilities in Field-Effect Transistors

  , Chemistry of Materials, Vol: 23, Pages: 4025-4031, ISSN: 0897-4756
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• Journal article
  Li X, Nazeeruddin MK, Thelakkat M, Barnes PRF, Vilar R, Durrant JRet al., 2011,

  Spectroelectrochemical studies of hole percolation on functionalised nanocrystalline TiO₂ films: a comparison of two different ruthenium complexes

  , PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol: 13, Pages: 1575-1584, ISSN: 1463-9076
  • Author Web Link
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  • Citations: 33
• Journal article
  Soon YW, Clarke TM, Zhang W, Agostinelli T, Kirkpatrick J, Dyer-Smith C, McCulloch I, Nelson J, Durrant JRet al., 2011,

  Energy versus electron transfer in organic solar cells: a comparison of the photophysics of two indenofluorene: fullerene blend films

  , Chemical Science, Vol: 2, Pages: 1111-1120, ISSN: 2041-6520

  In this paper, we compare the photophysics and photovoltaic device performance of two indenofluorene based polymers: poly[2,8-(6,6,12,12-tetraoctylindenofluorene)-co-4,7-(2,1,3-benzothiodiazole] (IF8BT) and poly[2,8-(6,6,12,12-tetraoctylindenofluorene)-co-5,5-(4[prime or minute],7[prime or minute]-di-2-thienyl-2[prime or minute],1[prime or minute],3[prime or minute]-benzothiodiazole] (IF8TBTT) blended with [6,6]-phenyl C61 butyric acid methyl ester (PCBM). Photovoltaic devices made with IF8TBTT exhibit greatly superior photocurrent generation and photovoltaic efficiency compared to those made with IF8BT. The poor device efficiency of IF8BT/PCBM devices is shown to result from efficient, ultrafast singlet Forster energy transfer from IF8BT to PCBM, with the resultant PCBM singlet exciton lacking sufficient energy to drive charge photogeneration. The higher photocurrent generation observed for IF8TBTT/PCBM devices is shown to result from IF8TBTT's relatively weak, red-shifted photoluminescence characteristics, which switches off the polymer to fullerene singlet energy transfer pathway. As a consequence, IF8TBTT singlet excitons are able to drive charge separation at the polymer/fullerene interface, resulting in efficient photocurrent generation. These results are discussed in terms of the impact of donor/acceptor energy transfer upon photophysics and energetics of charge photogeneration in organic photovoltaic devices. The relevance of these results to the design of polymers for organic photovoltaic applications is also discussed, particularly with regard to explaining why highly luminescent polymers developed for organic light emitting diode applications often give relatively poor performance in organic photovoltaic devices.

  • Abstract
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• Journal article
  Barnes PRF, Anderson AY, Durrant JR, O'Regan BCet al., 2011,

  Simulation and measurement of complete dye sensitised solar cells: including the influence of trapping, electrolyte, oxidised dyes and light intensity on steady state and transient device behaviour

  , PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol: 13, Pages: 5798-5816, ISSN: 1463-9076
  • Cite
  • Citations: 109
• Journal article
  Clarke TM, Ballantyne A, Shoaee S, Soon YW, Duffy W, Heeney M, McCulloch I, Nelson J, Durrant JRet al., 2010,

  Analysis of Charge Photogeneration as a Key Determinant of Photocurrent Density in Polymer: Fullerene Solar Cells

  , Adv. Mater., Vol: 22, Pages: 5287-5291, ISSN: 1521-4095
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• Journal article
  Maurano A, Hamilton R, Shuttle CG, Ballantyne AM, Nelson J, O'Regan B, Zhang W, McCulloch I, Azimi H, Morana M, Brabec CJ, Durrant JRet al., 2010,

  Recombination Dynamics as a Key Determinant of Open Circuit Voltage in Organic Bulk Heterojunction Solar Cells: A Comparison of Four Different Donor Polymers

  , ADVANCED MATERIALS, Vol: 22, Pages: 4987-+, ISSN: 0935-9648
  • Author Web Link
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  • Citations: 362
• Journal article
  Jamieson FC, Agostinelli T, Azimi H, Nelson J, Durrant JRet al., 2010,

  Field-Independent Charge Photogeneration in PCPDTBT/PC70BM Solar Cells

  , The Journal of Physical Chemistry Letters, Vol: 1, Pages: 3306-3310, ISSN: 1948-7185
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• Journal article
  Clarke TM, Durrant JR, 2010,

  Charge Photogeneration in Organic Solar Cells

  , CHEMICAL REVIEWS, Vol: 110, Pages: 6736-6767, ISSN: 0009-2665
  • Author Web Link
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  • Citations: 2103
• Journal article
  Eng MP, Barnes PRF, Durrant JR, 2010,

  Concentration-Dependent Hole Mobility and Recombination Coefficient in Bulk Heterojunctions Determined from Transient Absorption Spectroscopy

  , JOURNAL OF PHYSICAL CHEMISTRY LETTERS, Vol: 1, Pages: 3096-3100, ISSN: 1948-7185
  • Author Web Link
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  • Citations: 45
• Journal article
  Shoaee S, Clarke TM, Huang C, Barlow S, Marder SR, Heeney M, McCulloch I, Durrant JRet al., 2010,

  Acceptor Energy Level Control of Charge Photogeneration in Organic Donor/Acceptor Blends

  , JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol: 132, Pages: 12919-12926, ISSN: 0002-7863
  • Cite
  • Citations: 125
• Journal article
  Shuttle CG, Hamilton R, O'Regan BC, Nelson J, Durrant JRet al., 2010,

  Charge-density-based analysis of the current-voltage response of polythiophene/fullerene photovoltaic devices

  , PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, Vol: 107, Pages: 16448-16452, ISSN: 0027-8424
  • Author Web Link
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  • Citations: 259
• Journal article
  Said AJ, Poize G, Martini C, Ferry D, Marine W, Giorgio S, Fages F, Hocq J, Boucle J, Nelson J, Durrant JR, Ackermann Jet al., 2010,

  Hybrid Bulk Heterojunction Solar Cells Based on P3HT and Porphyrin-Modified ZnO Nanorods

  , JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 114, Pages: 11273-11278, ISSN: 1932-7447
  • Author Web Link
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  • Citations: 95
• Journal article
  Koops SE, Barnes PRF, O'Regan BC, Durrant JRet al., 2010,

  Kinetic Competition in a Coumarin Dye-Sensitized Solar Cell: Injection and Recombination Limitations upon Device Performance

  , JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 114, Pages: 8054-8061, ISSN: 1932-7447
  • Author Web Link
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  • Citations: 128
• Journal article
  Clarke TM, Ballantyne AM, Tierney S, Heeney M, Duffy W, McCulloch I, Nelson J, Durrant JRet al., 2010,

  Charge Photogeneration in Low Band Gap Polyselenophene/Fullerene Blend Films

  , JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 114, Pages: 8068-8075, ISSN: 1932-7447
  • Author Web Link
  • Cite
  • Citations: 58
• Journal article
  Hamilton R, Shuttle CG, O'Regan B, Hammant TC, Nelson J, Durrant JRet al., 2010,

  Recombination in Annealed and Nonannealed Polythiophene/Fullerene Solar Cells: Transient Photovoltage Studies versus Numerical Modeling

  , JOURNAL OF PHYSICAL CHEMISTRY LETTERS, Vol: 1, Pages: 1432-1436, ISSN: 1948-7185
  • Author Web Link
  • Cite
  • Citations: 157
• Journal article
  Leng WH, Barnes PRF, Juozapavicius M, O'Regan BC, Durrant JRet al., 2010,

  Electron Diffusion Length in Mesoporous Nanocrystalline TiO₂ Photoelectrodes during Water Oxidation

  , JOURNAL OF PHYSICAL CHEMISTRY LETTERS, Vol: 1, Pages: 967-972, ISSN: 1948-7185
  • Author Web Link
  • Cite
  • Citations: 134
• Journal article
  Cowan AJ, Tang J, Leng W, Durrant JR, Klug DRet al., 2010,

  Water Splitting by Nanocrystalline TiO₂ in a Complete Photoelectrochemical Cell Exhibits Efficiencies Limited by Charge Recombination

  , JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 114, Pages: 4208-4214, ISSN: 1932-7447
  • Author Web Link
  • Cite
  • Citations: 232
• Journal article
  Shuttle CG, Hamilton R, Nelson J, O'Regan BC, Durrant JRet al., 2010,

  Measurement of Charge-Density Dependence of Carrier Mobility in an Organic Semiconductor Blend

  , ADVANCED FUNCTIONAL MATERIALS, Vol: 20, Pages: 698-702, ISSN: 1616-301X
  • Author Web Link
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  • Citations: 156
• Journal article
  Dos Santos T, Morandeira A, Koops S, Mozer AJ, Tsekouras G, Dong Y, Wagner P, Wallace G, Earles JC, Gordon KC, Officer D, Durrant JRet al., 2010,

  Injection Limitations in a Series of Porphyrin Dye-Sensitized Solar Cells

  , JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 114, Pages: 3276-3279, ISSN: 1932-7447
  • Author Web Link
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  • Citations: 60
• Journal article
  Keivanidis PE, Clarke TM, Lilliu S, Agostinelli T, Macdonald JE, Durrant JR, Bradley DDC, Nelson Jet al., 2010,

  Dependence of Charge Separation Efficiency on Film Microstructure in Poly(3-hexylthiophene-2,5-diyl): [6,6]-Phenyl-C₆₁ Butyric Acid Methyl Ester Blend Films

  , JOURNAL OF PHYSICAL CHEMISTRY LETTERS, Vol: 1, Pages: 734-738, ISSN: 1948-7185
  • Author Web Link
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  • Citations: 99
• Journal article
  Atienzar P, Ishwara T, Illy BN, Ryan MP, O'Regan BC, Durrant JR, Nelson Jet al., 2010,

  Control of Photocurrent Generation in Polymer/ZnO Nanorod Solar Cells by Using a Solution-Processed TiO₂ Overlayer

  , JOURNAL OF PHYSICAL CHEMISTRY LETTERS, Vol: 1, Pages: 708-713, ISSN: 1948-7185
  • Cite
  • Citations: 63
• Journal article
  Benedetti JE, Goncalves AD, Formiga ALB, De Paoli M-A, Li X, Durrant JR, Nogueira AFet al., 2010,

  A polymer gel electrolyte composed of a poly(ethylene oxide) copolymer and the influence of its composition on the dynamics and performance of dye-sensitized solar cells

  , JOURNAL OF POWER SOURCES, Vol: 195, Pages: 1246-1255, ISSN: 0378-7753
  • Cite
  • Citations: 77
• Journal article
  Ballantyne AM, Ferenczi TAM, Campoy-Quiles M, Clarke TM, Maurano A, Wong KH, Zhang W, Stingelin-Stutzmann N, Kim J-S, Bradley DDC, Durrant JR, McCulloch I, Heeney M, Nelson J, Tierney S, Duffy W, Mueller C, Smith Pet al., 2010,

  Understanding the Influence of Morphology on Poly(3-hexylselenothiophene):PCBM Solar Cells

  , MACROMOLECULES, Vol: 43, Pages: 1169-1174, ISSN: 0024-9297
  • Author Web Link
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  • Citations: 91
• Journal article
  Anderson AY, Barnes PRF, Durrant JR, O'Regan BCet al., 2010,

  Simultaneous Transient Absorption and Transient Electrical Measurements on Operating Dye-Sensitized Solar Cells: Elucidating the Intermediates in Iodide Oxidation

  , JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 114, Pages: 1953-1958, ISSN: 1932-7447
  • Cite
  • Citations: 81
• Journal article
  Shoaee S, Eng MP, Espildora E, Luis Delgado J, Campo B, Martin N, Vanderzande D, Durrant JRet al., 2010,

  Influence of nanoscale phase separation on geminate <i>versus</i> bimolecular recombination in P3HT:fullerene blend films

  , ENERGY & ENVIRONMENTAL SCIENCE, Vol: 3, Pages: 971-976, ISSN: 1754-5692
  • Cite
  • Citations: 59
• Journal article
  McCall KL, Morandeira A, Durrant J, Yellowlees LJ, Robertson Net al., 2010,

  Characterisation of a ruthenium bipyridyl dye showing a long-lived charge-separated state on TiO₂ in the presence of I<SUP>-</SUP>/I₃<SUP>-</SUP>

  , DALTON TRANSACTIONS, Vol: 39, Pages: 4138-4145, ISSN: 1477-9226
  • Author Web Link
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  • Citations: 29

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